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Publications 2013 - 2015

Directed Manipulation of a Flavoprotein Photocycle
Citation key 102.2013.staudt
Author Staudt, H. and Hoesl, M. G. and Dreuw, A. and Serdjukow, S. and Oesterhelt, D. and Budisa, N. and Wachtveitl, J. and Grininger, M.
Pages 8463-8466
Year 2013
DOI 10.1002/anie.201302334
Journal Angew. Chem. Int. Ed. Engl.
Volume 52
Number 32
Abstract Tamed electrons: To manipulate a protein photocycle in a directed manner, the flavoprotein dodecin was endoscopically modified at its key amino acid tryptophan with substituents carefully selected by their structural and electronic influence. The approach is ideal in the precision of rational protein engineering, and allows correlating tryptophan ionization potentials and electron transfer rates in a Marcus model.
Link to original publication [1] Download Bibtex entry [2]
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