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Publications 2013 - 2015
| Citation key | 102.2013.staudt |
|---|---|
| Author | Staudt, H. and Hoesl, M. G. and Dreuw, A. and Serdjukow, S. and Oesterhelt, D. and Budisa, N. and Wachtveitl, J. and Grininger, M. |
| Pages | 8463-8466 |
| Year | 2013 |
| DOI | 10.1002/anie.201302334 |
| Journal | Angew. Chem. Int. Ed. Engl. |
| Volume | 52 |
| Number | 32 |
| Abstract | Tamed electrons: To manipulate a protein photocycle in a directed manner, the flavoprotein dodecin was endoscopically modified at its key amino acid tryptophan with substituents carefully selected by their structural and electronic influence. The approach is ideal in the precision of rational protein engineering, and allows correlating tryptophan ionization potentials and electron transfer rates in a Marcus model. |
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