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The regioselective synthesis of o-nitrobenzyl DOPA derivatives
Citation key 162.2017.Schneider
Author Schneider, T., and Martin, J., and Durkin, P. M., and Kubyshkin, V., and Budisa, N.
Pages 2691-2699
Year 2017
DOI SS-2016-12-0859-OP.R1
Journal SYNTHESIS
Volume 49
Abstract Photocaged DOPA derivatives may serve for non-invasive unmasking of the catechol fragment in biological systems. This would enable efficient control of the redox and metal-coordinating properties associated with the free catechol moiety, in particular, in biosynthetically produced adhesive proteins and synthetic peptides. Synthetic routes towards photocaged DOPA derivatives are reported herein. A new method for preparing para-alkylated DOPA starting from 3,4-dihydroxybenzaldehyde is described for the first time.
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